Chemical Composition of Hydraulic Fracturing Additives
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Red River Securities, LLC, Oil & Gas Exploration & Development, Plano, TX

Technology

Fracturing Insight

Fracing Composition

Tech Facts

 
 
 
 
  • Hydraulic fracturing, or “fracing,” has been used safely and effectively in the United States for over 60 years and is essential for extracting natural gas from formations such as the Barnett Shale.

    Hydraulic Fracturing Mixture Composition

    Freshwater and Sand: 99.51%

    Other: 0.49%

    Hydraulic Fracturing percentage diagram comparison of water, sand and chemical composition.
    • Acid

      0.123%

    • Friction Reducer

      0.088%

    • Surfactant

      0.085%

    • KCI

      0.06%

    • Gelling Agent

      0.056%

    • Scale Inhibitor

      0.043%

    • pH Adjusting Agent

      0.011%

    • Breaker

      0.01%

    • Crosslinker

      0.007%

    • Iron Control

      0.004%

    • Corrosion Inhibitor

      0.002%

    • Antibacterial Agent

      0.001%

    Additives within the Fracturing Solution

    • Additive Type

      Main Compound

      Purpose

      Common Use of Main Compound Additive

    • Acid

      Hydrochloric acid or muriatic acid

      Helps dissolve minerals and initiate cracks in the rock

      Swimming pool chemical and cleaner

    • Anti-bacterial agents

      Glutaraldehyde

      Eliminates bacteria in the water that produce corrosive by-products

      Disinfectant; Sterilizer for medical and dental equipment

    • Breaker

      Ammonium persulfate

      Allows a delayed break down of the gel used to thicken the water in order to suspend the sand

      Used in hair coloring, as a disinfectant,and in manufacture of common household plastics

    • Corrosion inhibitor

      n,n-dimethylformamide

      Prevents the corrosion of the pipe

      Used in pharmaceuticals, acrylic fibers and plastics

    • Crosslinker

      Borate salts

      Maintains fluid viscosity as temperature increases

      Used in laundry detergents, hand soaps and cosmetics

    • Friction reducer

      Petroleum distillate

      “Slicks” the water to minimize friction

      Used in cosmetics including hair, make-up, nail and skin products

    • Gel

      Guar gum or hydroxyethyl cellulose

      Thickens the water in order to suspend the sand

      Thickener used in cosmetics, baked goods, ice cream, toothpaste, sauces, and salad dressings

    • Iron control

      Citric acid

      Prevents precipitation of metal oxides

      Food additive; food and beverages; lemon juice ~7% citric acid

    • KCl

      Potassium chloride

      Creates a brine carrier fluid

      Used in low-sodium table salt substitute, medicines and IV fluids

    • Oxygen scavenger

      Ammonium bisulfite

      Removes oxygen from the water to protect the pipe from corrosion

      Used in cosmetics, food and beverage processing and water treatment

    • pH adjusting agent

      Sodium or potassium carbonate

      Maintains the effectiveness of other components, such as crosslinkers

      Used in laundry detergents, soap, water softener and dish washer detergents

    • Proppant

      Silica, quartz sand

      Allows the fractures to remain open so the gas can escape

      Drinking water filtration, play sand, concrete and brick mortar

    • Scale inhibitor

      Ethylene glycol

      Prevents scale deposits in the pipe

      Used in household cleanser, de-icer, paint and caulk

    • Surfactant

      Isopropanol

      Used to increase the viscosity of the fracture fluid

      Used in glass cleaner, multi-surface cleanser, antiperspirant, deodorant and hair coloring


     

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